Krausz, Professor Elmars R. BSc PhD Sydney FRACI -
Laser and Optical Spectroscopy
Hughes JL, Krausz E Novel characteristics of persistent
spectral hole-burning and hole-filling in Photosystem II core
complexes. J. Lumin. (2007), 127(1), 239-244. http://dx.doi.org/10.1016/j.jlumin.2007.02.030
Hughes JL, Krausz E Electronic spectroscopy. In
Applications of Physical Methods to Inorganic and Bioinorganic
Chemistry. Scott RA, Lukehart CM, eds. John Wiley and Sons:
Chichester, UK (2007), pp. 79-98.
Hughes JL, Smith PJ, Pace RJ, Krausz E Low-energy
absorption and luminescence of higher plant photosystem II core
samples. J. Lumin. (2007), 122-123, 284-287. http://dx.doi.org/10.1016/j.jlumin.2006.01.142
Krivokapic I, Zerara M, Lawson Daku M, Vargas A, Enachescu
C, Ambrus C, Tregenna-Piggott P, Amstutz N, Krausz E, Hauser A
Spin-crossover in cobalt(II) imine complexes. Coord. Chem.
Rev. (2007), 251(3+4), 364-378. http://dx.doi.org/10.1016/j.ccr.2006.05.006
Mahon DC, Mahon PJ, Creagh DC The effect of laser
excitation on the Raman microspectroscopy of nanoindentation-induced
silicon phase transformation. Nucl. Instrum. Methods Phys. Res.,
Sect. A (2007), 580(1), 430-433. http://dx.doi.org/10.1016/j.nima.2007.05.071
Hughes J L, Picorel R, Seibert M, Krausz E Photophysical
behavior and assignment of the low-energy chlorophyll states in the CP43
proximal antenna protein of higher plant Photosystem II.
Biochemistry (2006), 45(40), 12345-12357. http://dx.doi.org/10.1021/bi0614683
Hughes J L, Razeghifard R, Logue M, Oakley A, Wydrzynski T,
Krausz E Magneto-Optic Spectroscopy of a Protein Tetramer Binding Two
Exciton-Coupled Chlorophylls. J Am. Chem. Soc. (2006), 128(11),
3649-3658.http://dx.doi.org/10.1021/ja056576b
Hughes J L, Smith P J, Pace R J, Krausz E Spectral hole
burning at the low-energy absorption edge of photosystem II core
complexes. J. Lumin. (2006), 119-120, 298-303. http://dx.doi.org/10.1016/j.jlumin.2006.01.012
Hughes J L, Smith P, Pace R, Krausz E Charge separation
in photosystem II core complexes induced by 690-730 nm excitation at 1.7
K. Biochim. Biophys. Acta, Bioenerg. (2006), 1757(7), 841-851.
http://dx.doi.org/10.1016/j.bbabio.2006.05.035
Kelly J F, Samoc A, Samoc M, Krausz E R, Willis A C
Anisotropy of second-order nonlinear optical susceptibilities of
arsenic triiodide-sulfur addition complex: AsI3 ⋅
3S8. Opt. Commun. (2006), 264(1), 35-44. http://dx.doi.org/10.1016/j.optcom.2006.02.049
Lee A S, Mahon P J, Creagh D C Raman analysis of iron
gall inks on parchment. Vib. Spectrosc.(2006), 41(2), 170-175.
http://dx.doi.org/10.1016/j.vibspec.2005.11.006
Mahon P J, Oldham K B An examination of the conditions
resulting in a temporal convolution related to electrochemical
processes. J. Solid State Electrochem. (2006), 10(10), 785-791.
http://dx.doi.org/10.1007/s10008-006-0169-0
Vargas A, Zerara M, Krausz E, Hauser A, Lawson Daku L M
Density-functional theory investigation of the geometric, energetic,
and optical properties of the cobalt(II)tris(2,2'-bipyridine) complex in
the high-spin and the Jahn-Teller active low-spin states.J. Chem.
Theory Comput. (2006), 2(5), 1342-1359. http://dx.doi.org/10.1021/ct6001384
Hughes, J.L., Krausz, E., Smith, P.J., Pace, R.J., Riesen, H.
Probing the lowest energy chlorophyll a
states of Photosystem II via selective spectroscopy: new insights on
P680. Photosynth. Res. (2005), 84(1-3), 93-98. http://dx.doi.org/10.1007/s11120-004-7927-6
Krausz, E., Hughes, J.L., Smith, P.J., Pace, R.J.,
Peterson Årsköld, S.
Assignment of the
low-temperature fluorescence in oxygen-evolving Photosystem II.
Photosynth. Res. (2005), 84(1-3), 193-199. http://dx.doi.org/10.1007/s11120-004-7078-9
Krausz, E., Hughes, J.L., Smith, P.,
Pace, R., Peterson Årsköld, S. Oxygen-evolving Photosystem II
core complexes: a new paradigm based on the spectral identification of the
charge-separating state, the primary acceptor and assignment of
low-temperature fluorescence.Photochem. Photobiol. Sci. (2005),
4(9), 744-753. http://dx.doi.org/10.1039/b417905f
Krausz, E., Peterson Årsköld, S.
Identifying redox-active chromophores in Photosystem II by
low-temperature optical spectroscopies.
In Artificial Photosynthesis: From Basic Biology to Industrial Application.
Collings, A.F., Critchley, C., Eds. Wiley-VCH
Verlag GmbH & Co. KGaA: Weinheim (2005), pp. 87-107.
Kubik, M.
Monitoring colour and
fading: fluorescent pigments in works of art. Aust. J. Chem.
(2005), 58(3), 234. http://dx.doi.org/10.1071/CH04257
Mahon, P.J., Oldham, K.B.
Diffusion-controlled chronoamperometry at a disk electrode.
Anal. Chem. (2005), 77(18), 6100-6101. http://dx.doi.org/10.1021/ac051034y
Peterson Årsköld, S., Smith, P.J., Shen, J.-R., Pace, R.J.,
Krausz, E. Key cofactors of Photosystem
II cores from four organisms identified by 1.7-K absorption, CD and
MCD. Photosynth. Res. (2005), 84(1-3), 309-316. http://dx.doi.org/10.1007/s11120-005-2135-6
Razeghifard, M.R., Chen, M., Hughes,
J.L., Freeman, J., Krausz, E., Wydrzynski, T. Spectroscopic studies of
photosystem II in chlorophyll d-containing Acaryochloris
marina. Biochemistry (2005), 44(33), 11178-11187.
http://dx.doi.org/10.1021/bi048314c
Hughes, J.L., Prince, B.J., Krausz,
E., Smith, P.J., Pace, R.J., Riesen, H. Highly efficient spectral
hole-burning in oxygen-evolving photosystem II preparations. J.
Phys. Chem. B (2004), 108(29), 10428–10439.
Hughes, J.L., Prince, B.J.,
Peterson Årsköld, S., Krausz, E., Pace, R., Picorel, R.,
Seibert, M. Photo-conversion of chlorophylls in higher-plant CP43
characterized by persistent spectral hole burning at 1.7 K.
J. Lumin. (2004), 108(1–4), 131–136.
Hughes, J.L., Prince, B.J.,
Peterson Årsköld, S., Smith, P.J., Pace, R.J., Riesen, H.,
Krausz, E. The native reaction centre of photosystem II: a new
paradigm for P680. Aust. J. Chem. (2004), 57(12),
1179–1183.
Peterson Årsköld, S.,
Prince, B.J., Krausz, E., Smith, P.J., Pace, R.J., Picorel, R.,
Seibert, M. Low-temperature spectroscopy of fully active PSII
cores. Comparisons with CP43, CP47, D1/D2/cyt b559 fragments.
J. Lumin. (2004), 108(1–4), 97–100.
Prince, B.J., Krausz, E., Peterson
Årsköld, S., Smith, P. J., Pace, R.J. Persistent
spectral hole burning in oxygen-evolving photosystem II cores from
cyanobacteria and higher plants. J. Lumin. (2004),
108(1–4), 101–105.
Samoc, A., Samoc, M.,
Luther-Davies, B., Kelly, J.F., Krausz, E.R., Willis, A.C. New
second-order nonlinear octupolar materials. Mol. Cryst.
Liq. Cryst. (2004), 415, 179–195.
Ting, V., Liu, Y., Withers, R.L.,
Krausz, E. An electron diffraction and bond valence sum study of
the space group symmetries and structures of the photocatalytic 1:1
ordered A2InNbO6 double perovskites (A
= Ca2+, Sr2+, Ba2+). J. Solid
State Chem. (2004), 177(3), 979–986.
Krausz, E. Biophysics and biochemistry of Photosystem
II. The Physicist (2003), 40(1), 173-177.
Lilley, R.McC., Wang, X.-Q., Krausz, E., Andrews, T.J.
Complete spectra of the far-red chemiluminescence of the oxygenase
reaction of Mn2+ -activated ribulose-bisphosphate
carboxylase/oxygenase establish Mn2+ as the source. J.
Biol. Chem. (2003), 278(19), 16488-16493.
Peterson, S., Åhrling, K.A., Högblom, J.E.P.,
Styring, S. Flash-induced relaxation changes of the EPR signals from
the manganese cluster and YD reveal a light-adaptation
process of Photosystem II. Biochemistry (2003), 42,
2748-2758.
Peterson
Årsköld, S., Masters, V.M., Prince, B., Smith, P.J., Pace,
R.J., Krausz, E. Optical spectra of synechocystis and spinach
Photosystem II preparations at 1.7 K: identification of the
D1-pheophytin energies and Stark shifts. J. Am. Chem. Soc.
(2003), 125, 13063-13074.
Riley, M.J., Krausz, E.R., Stanco, A. New generation
MCD spectrometers. J. Inorg. Biochem. (2003), 96, 217.
Kelly, J.F., Krausz, E., Willis, A.C., Samoc, A., Samoc,
M. The crystal structure and second order nonlinear optical
susceptibility of the addition complex,
AsI3.3S8. Aust. J. Chem. (2002),
55,709-714.
Krausz, E. Photosynthesis, chasing the P680 dragon.
Chemistry in Australia (2002), 69(9), 24-26.
Smith, P.J., Peterson, S., Masters, V.M., Wydrzynski, T.,
Styring, S., Krausz, E., Pace, R.J. Magneto-optical measurements of
the pigments in fully active photosystem II core complexes from
plants. Biochemistry (2002), 41, 1981-1989.
Masters, V.M., Riley, M.J., Hitchman, M.A. Structural
dynamics in
(ND4)2[Cu(D2O)6](SO4)
2. Inorg. Chem. (2001), 40(5), 443-449.
Masters, V.M., Riley, M.J., Hitchman, M.A., Simmons, C.
Clarification of the crystal structure of
[(HC(Ph2PO)3)2Cu](ClO4)22·H
2O. Inorg. Chem. (2001), 40(17), 4478-4480.
Masters, V.M., Smith, P., Krausz, E., Pace, R. Stark
shifts and exciton coupling in PSII 'supercores’. J.
Luminescence (2001), 94-95, 267-270.
Purchase, R., Sellars, M.J., Krausz, E., and Manson, N.B.
Electric-field-induced broadening of spectral holes in zinc
phthalocyanine. Chemical Physics Letters, 327, 189-196
(2000).
Purchase, R., Sellars, M.J., Krausz, E., and Manson, N.B.
Magneto-optic measurements of spectral holes in metallo-porphyrin
derivatives in polymer matrices.Physical Chemistry Chemical
Physics, 2, 3993-3999 (2000).
Riesen, H., and Dubicki, L. On the nature of the
trigonal fields in hexaaquachromium(III) in guanidinium aluminum sulfate
hexahydrate. Inorganic Chemistry, 39(10), 2206-2211(2000).
Riesen, H., Wallace, L., and Krausz, E. Probing the
electronic structure of coordination compounds by transient spectral
hole-burning. Applications to specifically deuterated
[Ru(bpy)3]2+ complexes.Inorganic
Chemistry, 39, 5044-5052 (2000).
Sellars, M.J., Pryde, F.J., Manson, N.B., and Krausz, E.
50kHz absorption line in
Y2SiO5:Eu3+.Journal of
Luminescence, 87-89, 833-835 (2000).
Bridgeman, A.J., Halcrow, M.A., Jones, M., Krausz, E., and
Solanki N.K. The ground state of a tetragonally compressed copper(II)
complex. Chemical Physics Letters, 314, 176-181
(1999).
Hurst, J.K., Wormell, P., Krausz, E., and Lacey, A.R.
The electronic spectrum of 1,4,5,8-tetraazanapthalene.
Chemical Physics, 246, 229-246 (1999).
Krausz, E. and Riesen, H. Laser spectroscopy. In
Inorganic Electronic Structure and Spectroscopy, Eds. E.I.
Solomon and A.P.B. Lever, Wiley, New York, Volume 1, Chapter 6, pp
307-352 (1999).
Munn, R.W., Kelly, J.F., and Aicken, F.M. Analysis of
the linear and non-linear optics of crystals of CHI3,
S8 and their 1:3 complex. Chemical Physics,
245, 227-241 (1999).
Purchase, R., Plagemann, B., Krausz, E., and Wild, U.P.
Electric-field induced broadening of spectral holes in zinc
phthalocyanine. Chemical Physics Letters, 309, 29-34
(1999).
Riley, M., Krausz, E., Manson, N.B., and Henderson, B.
Selectively excited luminescence and magnetic circular dichroism of
Cr4+doped YAG and YGG. Physical Review B,
59, 1850-1856 (1999).
Purchase, R., Krausz, E. and Williamson, B.E.
Magneto-optic measurements of spectral holes. Journal of
Luminescence 76 & 77, 339-343 (1998).
Riesen, H. and Krausz, E. Transient spectral
hole-burning and excitation line narrowing in the 3MLCT
transitions of
[Zn(2,2'-bipyridine)3](ClO4)2:Ru(II).
Chemical Physics Letters, 287, 338-394(1998).
Riesen, H., Wallace, L. and Krausz, E. Dynamical
processes in the lowest-excited triplet metal-to-ligand charge transfer
states of ruthenium and osmium diimmine complexes in crystals.
International Reviews in Physical Chemistry, 16, 291-359
(1997).
Krausz, E. and Riesen, H. Developments in laser
selective spectroscopy and photophysics of d6
metal-(di-imine) complexes. Coordination Chemistry Reviews,
159, 9-40 (1997).
Krausz, E. and Riesen, H. Chemical applications of
laser narrowing spectroscopy. Journal of Molecular Structure,
406, 61-74 (1997).
Gasyna, Z. and Schatz, P.N. Analysis of the
intervalence band in the oxidised photosynthetic bacterial reaction
center. Journal of Physical Chemistry, 100, 1445-1448
(1996).
Hauser, A., Riesen, H., Pellaux, R. and Decurtins, S.
Resonant excitation energy transfer in
[Rh(bpy)3][NaCr(ox)3]ClO4.
Chemical Physics Letters, 261, 313-317 (1996).
Kang, H.W., Moran, G. and Krausz, E. Magnetic circular
dichroism spectroscopy of the hexacyano complexes of Ru(III) and
Os(III). Inorganica Chimica Acta, 249, 231-235 (1996).
Krausz, E., Riesen, H., Schatz, P.N., Gasyna, Z., Dunford,
C.L. and Williamson, B.E. Magneto-optical hole burning studies of
matrix isolated phthalocyanines. Journal of Luminescence,
66 & 67, 19-24 (1996).
Riesen, H. and Krausz, E. Applications of laser
spectroscopy to triplet metal-to-ligand charge transfer transitions.
Journal of Luminescence, 66 & 67, 496-505
(1996).
Riesen, H. and Krausz, E. Stark effects in the
lowest-excited 3MLCT states of
[Ru(bpy)(bpy-d8)2]2+ in
[Zn(bpy)3](ClO4)2
(bpy = 2,2’-bipyridine). Chemical Physics
Letters, 260, 130-135 (1996).
Riesen, H., Wallace, L. and Krausz, E. Intramolecular
mini-excitons in the series
[Os(bpy)3-x(bpy-d8)x]2+
(x=0-3) in [Zn(bpy)3](ClO4)2 and
[Ru(bpy)3](ClO4)2,
(bpy = 2,2’-bipyridine). Molecular Physics,
87, 1299-1316 (1996).
Riesen, H., Wallace, L. and Krausz, E. Localized
3MLCT transitions in
[Ru(bpy)3-x(bpy-6-6’-d2)x]
2+ (x=0-3, bpy = 2,2-bipyridine). Probing minimally
perturbed chromophores. Journal of Physical Chemistry,
100, 17138-17144 (1996).
Riesen, H., Wallace, L. and Krausz, E. Localized
3MLCT excitations of
[Ru(bpy)3-x(bpy-6-6’-d2)x]
2+ (x=0-3) in [Zn(bpy)3](ClO4)2
(bpy = 2,2’-bipyridine). Inorganic Chemistry,
35, 6908-6909 (1996).
Riesen, H., Wallace, L. and Krausz, E. Vibrational
sidelines in the localized 3MLCT emission of
[Ru(bpy)2(bpz)]2+ in
[Zn(bpy)3](ClO4)2
(bpy = 2,2’-bipyridine,
(bpz = 2,2’-bipyrazine). Journal of Physical
Chemistry, 100, 4390-4394 (1996).
Riley, M., Boutchard, C., Krausz, E. and Hitchman, M.A.
Observation of a magnetic dipole origin in the spectrum of the square
planar CuCl42- ion. Chemical Physics
Letters, 254, 403-409 (1996).
Stranger, R., Dubicki, L. and Krausz, E.
Magneto-optical investigation of the exchange-coupled dimer
Cs3Mo2Br9. Inorganic
Chemistry, 35, 4218-4226 (1996).
von Arx, M.E., Hauser, A., Riesen, H., Pellaux, R. and Decurtins, S. Resonant and phonon-assisted excitation energy transfer in the R1 line of [Cr(ox)3]3-. Physical Review B, 54, 15800-15807 (1996).