Humphrey, Professor Mark G. BSc (Hons) PhD DSc
Adelaide, FRACI, FRSC - Organometallic Chemistry and Molecular
Materials
Dalton GT, Cifuentes MP, Watson LA, Petrie S, Stranger R,
Samoc M, Humphrey MG Organometallic complexes for nonlinear optics. 42.
Syntheses, linear, and nonlinear optical properties of ligated
metal-functionalized oligo(p-phenyleneethynylene)s. Inorg.
Chem. (2009), 48(14), 6534-6547. http://dx.doi.org/10.1021/ic900469y
Fox MA, Farmer JD, Roberts RL, Humphrey MG, Low PJ
Noninnocent ligand behavior in diruthenium complexes containing a
1,3-diethynylbenzene bridge. Organometallics (2009), 28(17),
5266-5269. http://dx.doi.org/10.1021/om900200n
Gauthier N, Tchouar N, Justaud F, Argouarch G, Cifuentes MP,
Toupet L, Touchard D, Halet J-F, Rigaut S, Humphrey MG, Costuas K, Paul F
Bonding and electron delocalization in ruthenium(III)
σ arylacetylide radicals
[trans-Cl(η2-dppe)2RuC≡C(4-C6H4X)]+
(X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2):
misleading aspects of the ESR anisotropy. Organometallics
(2009), 28(7), 2253-2266. http://dx.doi.org/10.1021/om801138q
Ge Q, Corkery TC, Humphrey MG, Samoc M, Hor TSA
Organobimetallic RuII-ReI 4 ethynylpyridyl
complexes: structures and non-linear optical properties. Dalton
Trans. (2009), (31), 6192-6200. http://dx.doi.org/10.1039/b902800e
Ge Q, Dalton GT, Humphrey MG, Samoc M, Hor TSA Structural
and nonlinear optical properties of aligned heterotrinuclear
[RuII-(spacer)-MII-(spacer)-RuII]
complexes (M = Pd, Pt; spacer = 4-ethynylpyridine). Chem. Asian
J. (2009), 4(6), 998-1005. http://dx.doi.org/10.1002/asia.200900065
Green KA, Cifuentes MP, Corkery TC, Samoc M, Humphrey MG
Switching the cubic nonlinear optical properties of an electro-, halo-,
and photochromic ruthenium alkynyl complex across six states.
Angew. Chem. Int. Ed. (2009), 48(42), 7867-7870. http://dx.doi.org/10.1002/anie.200903027
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Fairlamb I, Lynam JM,
eds. Specialist Periodical Reports Vol. 35, Royal Society of Chemistry:
Cambridge, UK (2009), pp. 234-259. http://dx.doi.org/10.1039/b801383g
Rigamonti L, Babgi B, Cifuentes MP, Roberts RL, Petrie S,
Stranger R, Righetto S, Teshome A, Asselberghs I, Clays K, Humphrey MG
Organometallic complexes for nonlinear optics. 43. Quadratic optical
nonlinearities of dipolar alkynylruthenium complexes with
phenyleneethynylene/phenylenevinylene bridges. Inorg. Chem.
(2009), 48(8), 3562-3572. http://dx.doi.org/10.1021/ic801953z
Roberts RL, Schwich T, Corkery TC, Cifuentes MP, Green KA,
Farmer JD, Low PJ, Marder TB, Samoc M, Humphrey MG Organometallic
complexes for nonlinear optics. 45. Dispersion of the third-order
nonlinear optical properties of triphenylamine-cored alkynylruthenium
dendrimers. Adv. Mater. (2009), 21(22), 2318-2322. http://dx.doi.org/10.1002/adma.200803669
Fondum TN, Green KA, Randles MD, Cifuentes MP, Willis AC,
Teshome A, Asselberghs I, Clays K, Humphrey MG Organometallic complexes
for nonlinear optics. 41: Syntheses and quadratic NLO properties of
4-{4-(4-nitrophenyl)diazophenyl}ethynylphenylethynyl complexes. J.
Organomet. Chem. (2008), 693(8-9), 1605-1613. http://dx.doi.org/10.1016/j.jorganchem.2007.11.004
Gauthier N, Argouarch G, Paul F, Humphrey MG, Toupet L,
Ababou-Girard S, Sabbah H, Hapiot P, Fabre B Silicon surface-bound
redox-active conjugated wires derived from mono- and dinuclear iron(II)
and ruthenium(II) oligo(phenyleneethynylene) complexes. Adv.
Mater. (2008), 20(10), 1952-1956 http://dx.doi.org/10.1002/adma.200800324
Gauthier N, Olivier C, Rigaut S, Touchard D, Roisnel T,
Humphrey MG, Paul F Intramolecular optical electron-transfer in
mixed-valent dinuclear iron-ruthenium complexes featuring a
1,4-diethynylaryl spacer.Organometallics (2008), 27(6),
1063-1072. http://dx.doi.org/10.1021/om700584m
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Fairlamb I, Lynam JM,
eds. Specialist Periodical Reports Vol. 34, Royal Society of Chemistry:
Cambridge, UK (2008), 166-190. http://dx.doi.org/10.1039/b609350g
Morrall JP, Dalton GT, Humphrey MG, Samoc M
Organotransition metal complexes for nonlinear optics. In
Advances in Organometallic Chemistry, Vol. 55. West R, Hill AF,
Fink MJ, eds. Academic Press: San Diego, USA (2008), pp. 61-136.
http://dx.doi.org/10.1016/S0065-3055(07)55002-1
Samoc M, Dalton GT, Gladysz JA, Zheng Q, Velkov Y,
Ågren H, Norman P, Humphrey MG Cubic nonlinear optical properties
of platinum-terminated polyynediyl chains. Inorg. Chem.
(2008), 47(21), 9946-9957.
http://dx.doi.org/10.1021/ic801145c
Samoc M, Samoc A, Dalton GT, Cifuentes MP, Humphrey MG,
Fleitz PA Dispersion of the complex cubic nonlinearity in two-photon
absorbing organic and organometallic chromophores. In Proc. SPIE,
Vol. 6801 - Photonics: Design, Technology, and Packaging III.
Krolikowski WZ, Soukoulis CM, Lam PK, Davis TJ, Fan S, Kivshar YS, eds.
SPIE: Bellingham, USA (2008), 68011O/1-6. http://dx.doi.org/10.1117/12.760849
Samoc M, Samoc A, Humphrey MG, Cifuentes MP, Luther-Davies
B, Fleitz PA Z-scan studies of dispersion of the complex third-order
nonlinearity of nonlinear absorbing chromophores.Mol. Cryst. Liq.
Cryst. (2008), 485, 894-902. http://dx.doi.org/10.1080/15421400801924714
Zhang C, Cao Y, Zhang J, Meng S, Matsumoto T, Song Y, Ma J,
Chen Z, Tatsumi K, Humphrey MG Modulation of third-order nonlinear
optical properties by backbone modification of polymeric pillared-layer
heterometallic clusters. Adv. Mater. (2008), 20(10), 1870-1875
http://dx.doi.org/10.1002/adma.200702645
Zhang J, Song Y, Yang J, Humphrey MG, Zhang C A
single-bridge strategy for synthesis of a 3D-heterobimetallic cluster with
a heavily distorted diamondoid topology and enhanced third-order nonlinear
optical properties. Cryst. Growth Des. (2008), 8(2), 387-390.
http://dx.doi.org/10.1021/cg700877n
Feuvrie C, Maury O, Le Bozec H, Ledoux I, Morrall JP, Dalton
GT, Samoc M, Humphrey MG Nonlinear optical and two-photon absorption
properties of octupolar tris(bipyridyl) metal complexes. J. Phys.
Chem. A (2007), 111(37), 8980-8985. http://dx.doi.org/10.1021/jp0735381
Humphrey MG, Cifuentes MP Medium- and high-nuclearity
clusters of Ru/Os. In Comprehensive Organometallic Chemistry III,
Vol. 6 - Compounds of Group 8. Mingos DM, Crabtree RH, Bruce M, eds.
Elsevier: Oxford, UK (2007), 973-1044.
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Green M, ed. Specialist
Periodical Reports Vol. 33, Royal Society of Chemistry: Cambridge, UK
(2007), 179-229. http://dx.doi.org/10.1039/9781847558503-00179
Humphrey MG, Cifuentes MP, Samoc M Alkynylruthenium
dendrimers: syntheses and multiphoton absorption. Polym. Prepr.
(Am. Chem. Soc., Div. Polym. Chem.) (2007), 48(2), 525-526.
Powell CE, Cifuentes MP, Humphrey MG, Willis AC, Morrall JP,
Samoc M Organometallic complexes for nonlinear optics. 37: Synthesis
and third-order nonlinear optical properties of a hexarutheniumtriplatinum
dendrimer. Polyhedron (2007), 26(2), 284-289. http://dx.doi.org/10.1016/j.poly.2006.05.007
Powell CE, Hurst SK, Morrall JP, Cifuentes MP, Roberts RL,
Samoc M, Humphrey MG Organometallic complexes for nonlinear optics. 39.
Syntheses and third-order nonlinear optical properties of first-generation
peripherally-metalated arylalkynyl dendrimers.Organometallics
(2007), 26(18), 4456-4463. http://dx.doi.org/10.1021/om700398n
Randles MD, Lucas NT, Cifuentes MP, Humphrey MG, Smith MK,
Willis AC, Samoc M Mixed-metal cluster chemistry. 30. Syntheses and
optical limiting properties of cluster-containing oligo- and
polyurethanes. Macromolecules (2007), 40(22), 7807-7818.
http://dx.doi.org/10.1021/ma0710582
Randles MD, Willis AC, Cifuentes MP, Humphrey MG
High-nuclearity ruthenium carbonyl cluster chemistry. 8: Phosphine
activation, CO insertion, and deruthenation at a phosphido cluster - X-ray
structures of
[ppn][Ru8(μ8-P)(μ-CO)2(CO)20]
and
[ppn][Ru7(μ7-P)(μ-η2-OCPh)(μ-PPh2)(μ-CO)(CO)17].
J. Organomet. Chem. (2007), 692(21), 4467-4472. http://dx.doi.org/10.1016/j.jorganchem.2007.03.040
Samoc M, Morrall JP, Dalton GT, Cifuentes MP, Humphrey MG
Two-photon and three-photon absorption in an organometallic
dendrimer. Angew. Chem. Int. Ed. (2007), 46(5), 731-733.
http://dx.doi.org/10.1002/anie.200602341
Viau L, Willis AC, Humphrey MG Ruthenium cluster
chemistry: monodentate bis(diphenylphosphino)acetylene-ligated cluster
modules in chain and dendrimer formation. J. Organomet. Chem.
(2007), 692(10), 2086-2091. http://dx.doi.org/10.1016/j.jorganchem.2007.01.027
Cifuentes MP, Powell CE, Morrall JP, McDonagh AM, Lucas NT,
Humphrey MG, Samoc M, Houbrechts S, Asselberghs I, Clays K, Persoons A,
Isoshima T Electrochemical, spectroelectrochemical, and molecular
quadratic and cubic nonlinear optical properties of alkynylruthenium
dendrimers. J. Am. Chem. Soc. (2006), 128(33), 10819-10832.
http://dx.doi.org/10.1021/ja062246v
Humphrey MG, Cifuentes MP, Samoc M Metal alkynyl
dendrimers with switchable NLO properties.PMSE Prepr. (2006),
95, 149.
Humphrey MG, Powell CE, Cifuentes MP, Morrall JP, Samoc M
Syntheses and nonlinear optical properties of alkynylruthenium
dendrimers. In Metal-Containing and Metallo-Supramolecular Polymers
and Materials. Schubert US, Newkome GR, Manners I, eds. ACS Symposium
Series 928, American Chemical Society: Washington, DC (2006), pp. 258-272.
Morrall JPL, Cifuentes MP, Humphrey MG, Kellens R, Robijns
E, Asselberghs I, Clays K, Persoons A, Samoc M, Willis AC
Organometallic complexes for nonlinear optics. Part 36. Quadratic and
cubic optical nonlinearities of 4-fluorophenylethynyl- and
4-nitro-(E)-stilbenylruthenium complexes. Inorg. Chim.
Acta (2006), 359(3), 998-1005.http://dx.doi.org/10.1016/j.ica.2005.09.012
Morrall JP, Humphrey MG, Dalton GT, Cifuentes MP, Samoc M
NLO Properties of metal alkynyl and related complexes. In
Nonlinear Optical Properties of Matter: From Molecules to Condensed
Phases. Papadopoulos MG, Leszczynski J, Sadlej AJ, eds. Springer:
Dordrecht, (2006), Chapter 17, pp. 537-569.
Randles MD, Willis AC, Cifuentes MP, Humphrey MG
Bis(triphenylphosphoranylidene)ammonium
docosacarbonyl(μ8-phosphido)octaruthenate
chloroform solvate. Acta Crystallogr. E (2006), 62(9),
m2350-m2351. http://dx.doi.org/10.1107/S1600536806034052
Samoc M, Gauthier N, Cifuentes MP, Paul F, Lapinte C,
Humphrey MG Electrochemical switching of the cubic nonlinear optical
properties of an aryldiethynyl-linked heterobimetallic complex between
three distinct states. Angew. Chem. Int. Ed. (2006), 45(44),
7536-7539. http://dx.doi.org/10.1002/anie.200602684[Erratum: Angew. Chem.
Int. Ed. (2008), 47(4), 629. http://dx.doi.org/10.1002/anie.200890004]
Usher AJ, Lucas NT, Dalton GT, Randles MD, Viau L, Humphrey
MG, Petrie S, Stranger R, Willis AC, Rae AD Mixed-metal cluster
chemistry. 29. Core expansion and ligand-driven metal exchange at group
6-iridium clusters. Inorg. Chem. (2006), 45(26),
10859-10872.http://dx.doi.org/10.1021/ic061736l
Willis AC, Mahdi WK, Humphrey, MG
(OC-6-13)-Bis[5-(bromo-2-(4-bromophenyldiazenyl)phenyl]dicarbonylruthenium(II)
with mutually trans N-donor atoms. Acta Crystallogr.
E (2006), 62(1), m118-m119. http://dx.doi.org/10.1107/S1600536805041358
Willis AC, Mahdi WK, Humphrey MG
(OC-6-32)-Bis[5-bromo-2-(4-bromophenyldiazenyl)phenyl]dicarbonylruthenium(II).
Acta Crystallogr. E (2006), 62(1), m116-m117. http://dx.doi.org/10.1107/S1600536805041322
Willis AC, Powell CE, Humphrey MG
trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane-κ2P,P'](phenylethynyl)ruthenium(II)
hexafluorophosphate ethanol hemisolvate. Acta Crystallogr. E
(2006), 62(10), m2473-m2475. http://dx.doi.org/10.1107/S1600536806035252
Dalton GT, Viau L, Waterman SM, Humphrey MG, Bruce MI, Low
PJ, Roberts RL, Willis AC, Koutsantonis GA, Skelton BW, White AH
Mixed-metal cluster chemistry. 28. Core enlargement of tungsten-iridium
clusters with alkynyl, ethynediyl and butadiynediyl reagents.
Inorg. Chem. (2005), 44(9), 3261-3269. http://dx.doi.org/10.1021/ic050040+
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Green M, ed. Specialist
Periodical Reports Vol. 32, Royal Society of Chemistry: Cambridge, UK
(2005), 214-263. http://dx.doi.org/10.1039/9781847558497-00214
Humphrey MG, Lockhart-Gillett B, Samoc M, Skelton BW,
Tolhurst V-A, White AH, Wilson AJ, Yates BF Synthesis, structure and
optical limiting properties of organoruthenium-chalcogenide clusters.
J. Organomet. Chem. (2005), 690(6), 1487-1497. http://dx.doi.org/10.1016/j.jorganchem.2004.12.018
Humphrey PA, Turner P, Masters AF, Field LD, Cifuentes MP,
Humphrey MG, Asselberghs I, Persoons A, Samoc M Synthesis and
non-linear optical properties of
(η5-pentaphenylcyclopentadienyl)dicarbonylruthenium(II)
σ-alkenyl complexes. Inorg. Chim. Acta (2005), 358(5),
1663-1672. http://dx.doi.org/10.1016/j.ica.2004.09.045
Lucas NT, Humphrey MG, Willis AC
[μ8-η4-2,5-Bis(oct-1-ynyl)thiophene]bis[octacarbonylbis(η5-methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum]
dichloromethane hemisolvate. Acta Crystallogr. E (2005), 61(3),
m463-m464. http://dx.doi.org/10.1107/S160053680500214X
Samoc M, Humphrey MG, Cifuentes MP Nonlinear absorption
and nonlinear refraction in ruthenium alkynyl complexes. Chin. Opt.
Lett. (2005), 3(0s), 23-25. http://www.opticsjournal.net/abstract.htm?aid=OJ070305000007GcJfLi
Willis AC, Mahdi W, Humphrey MG
Bis(μ3-4-bromophenylimido)tris(tricarbonylruthenium)
(2 Ru-Ru). Acta Crystallogr. E (2005), 61(11),
m2335-m2337. http://dx.doi.org/10.1107/S1600536805032885
Cifuentes MP, Humphrey MG Alkynyl compounds and nonlinear
optics. J. Organomet. Chem. (2004), 689(24), 3968-3981.
http://dx.doi.org/10.1016/j.jorganchem.2004.06.027
(Invited Review - Special Issue on Reflections on Major Discoveries and
Future Perspectives).
Dalton GT, Willis AC, Humphrey MG Mixed-metal cluster
chemistry. 27. Coupling of diphenylbuta-1,3-diyne and CO at
tungsten-triiridium cluster cores. J. Cluster Sci. (2004),
15(3), 291-300. http://dx.doi.org/10.1023/B:JOCL.0000041196.07154.9f
Humphrey MG Towards oligoclusters - chemistry and
properties. In Organometallic and Coordination Clusters and
Polymers: Syntheses and Applications, Abd-El-Aziz AS, Harvey PD, eds.
Macromolecular Symposia, Volume 209, Wiley-VCH: Weinheim (2004),
pp. 1-22. http://dx.doi.org/10.1002/masy.200450501
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Green M, ed. Specialist
Periodical Reports Vol. 31, Royal Society of Chemistry: Cambridge, UK
(2004), 297-348. http://dx.doi.org/10.1039/9781847554208-00297
Humphrey MG, Powell CE, Cifuentes MP, Morrall JP, Samoc M
Syntheses and nonlinear optical properties of alkynylruthenium
dendrimers. Polym. Prepr. (2004), 45(1), 367-368.
Powell CE, Humphrey MG Nonlinear optical properties of
transition metal acetylides and their derivatives. Coord. Chem.
Rev. (2004), 248(7-8), 725-756. http://dx.doi.org/10.1016/j.ccr.2004.03.009
Powell CE, Morrall JP, Ward SA, Cifuentes MP, Notaras EGA,
Samoc M, Humphrey MG Dispersion of the third-order nonlinear optical
properties of an organometallic dendrimer. J. Am. Chem. Soc.
(2004), 126(39), 12234-12235. http://dx.doi.org/10.1021/ja048608l
Samoc M, Powell CE, Morrall JP, Ward SA, Cifuentes MP,
Notaras EGA, Humphrey MG Two-photon absorption, absorption saturation
and dispersion of the real and imaginary parts of the third-order optical
nonlinearity in organometallic dendrimers. SPIE Proc., Int. Soc.
Opt. Eng. (2004), 5516, 86-96. http://dx.doi.org/10.1117/12.563676
Usher AJ, Dalton GT, Lucas NT, Waterman SM, Petrie S,
Stranger R, Humphrey MG, Willis AC Mixed-metal cluster chemistry. 26.
Proclivity for "all-terminal" or "plane-of-bridging-carbonyls" ligand
disposition in tungsten-triiridium clusters. J. Organomet.
Chem. (2004), 689(1), 50-57. http://dx.doi.org/10.1016/j.jorganchem.2003.09.026
Willis AC, Dalton GT, Morrall JP, Cifuentes MP, Humphrey MG
cis,cis,cis-(Aqua)bis{bis(diphenylphosphino)methane-k2P,P'}chlororuthenium(II)
hexafluorophosphate methanol 1.73-solvate. Acta Crystallogr. E
(2004), 60(8), m1122-m1123. http://dx.doi.org/10.1107/S1600536804016253
Willis AC, Dalton GT, Humphrey MG
Heptacarbonylbis(μ3-η2-diphenylacetylene)(η5-pentamethylcyclopentadienyl)triiridiumtungsten.Acta
Crystallogr. E. (2004), 60(4), m458-m459. http://dx.doi.org/10.1107/S1600536804006439
Garriga JM, Llusar R, Uriel S, Vicent C,
Usher AJ, Lucas NT, Humphrey MG, Samoc M
Synthesis and third-order nonlinear optical properties of
[Mo3(μ3-S)(μ2-S2)3]4+
clusters with maleonitriledithiolate, oxalate and thiocyanate ligands.
J. Chem. Soc., Dalton Trans. (2003), (23), 4546-4551. http://dx.doi.org/10.1039/b307753e
Humphrey MG Preface. J. Organomet. Chem.
(2003), 670(1-2), 1. http://dx.doi.org/10.1016/S0022-328X(03)00007-X
Humphrey MG, Cifuentes MP, Samoc M, Isoshima T, Persoons A
Hyper-structured alkynylruthenium complexes: effect of dimensional
evolution on NLO properties. In Perspectives in Organometallic
Chemistry, Screttas CG, Steele BR, eds. Special Publication No. 287,
Royal Society of Chemistry: Cambridge, UK (2003), pp. 100-110. http://dx.doi.org/10.1039/9781847551641-00100
Humphrey MG, Mingos DMP, eds. Recent developments in
metal alkynyl organometallic chemistry. J. Organomet. Chem.
(2003), 670(1-2), 1-262.
Hurst SK, Humphrey MG, Morrall JP, Cifuentes MP, Samoc M,
Luther-Davies B, Heath GA, Willis AC Organometallic complexes for
nonlinear optics. Part 31. Cubic hyperpolarizabilities of
ferrocenyl-linked gold and ruthenium complexes. J. Organomet.
Chem. (2003), 670(1-2), 56-65. http://dx.doi.org/10.1016/S0022-328X(02)02131-9
Hurst SK, Lucas NT, Humphrey MG, Isoshima T, Wostyn K,
Asselberghs I, Clays K, Persoons A, Samoc M, Luther-Davies B
Organometallic complexes for nonlinear optics. Part 29. Quadratic and
cubic hyperpolarizabilities of stilbenylethynyl-gold and -ruthenium
complexes. Inorg. Chim. Acta (2003), 350, 62-76. http://dx.doi.org/10.1016/S0020-1693(02)01497-4
Lucas NT, Notaras EGA, Cifuentes MP, Humphrey MG
Mixed-metal cluster chemistry. 21. Synthesis and crystallographic and
electrochemical studies of alkyne-coordinated group 6-iridium clusters
linked by phenylenevinylene groups. Organometallics (2003),
22(2), 284-301. http://dx.doi.org/10.1021/om020203r
Lucas NT, Notaras EGA, Humphrey MG, Samoc M, Luther-Davies B
Syntheses, characterization, and optical limiting properties of
heterometallic cluster-containing polymers. SPIE Proc., Int. Soc.
Opt. Eng. (2003), 5212, 318-325. http://dx.doi.org/10.1117/12.505289
Lucas NT, Notaras EGA, Petrie S, Stranger R, Humphrey MG
Mixed-metal cluster chemistry. 22. Synthesis and crystallographic,
electrochemical and theoretical studies of alkyne-coordinated group
6-iridium clusters linked by phenyleneethynylene
groups.Organometallics (2003), 22(4), 708-721. http://dx.doi.org/10.1021/om020910k
McDonagh AM, Powell CE, Morrall JP, Cifuentes MP, Humphrey
MG Convergent synthesis of alkynylbis(bidentate phosphine)ruthenium
dendrimers.Organometallics (2003), 22(7), 1402-1413.
http://dx.doi.org/10.1021/om020975n
Morrall JP, Powell CE, Stranger R, Cifuentes MP, Humphrey
MG, Heath GA Organometallic Complexes for nonlinear optics. Part 32:
Synthesis, optical spectroscopy and theoretical studies of some osmium
alkynyl complexes. J. Organomet. Chem. (2003), 670(1-2),
248-255. http://dx.doi.org/10.1016/S0022-328X(03)00039-1
Notaras EGA, Lucas NT, Humphrey MG, Willis AC, Rae AD
Mixed-metal cluster chemistry. 23. Synthesis and crystallographic and
electrochemical studies of alkyne-coordinated Group 6-iridium clusters
linked by heterocyclic groups. Organometallics (2003), 22(18),
3659-3670 (2003). http://dx.doi.org/10.1021/om030253b
Powell CE, Cifuentes MP, McDonagh AM, Hurst S, Lucas NT,
Delfs CD, Stranger R, Humphrey MG, Houbrechts S, Asselberghs I, Persoons
A, Hockless DCR Organometallic complexes for nonlinear optics. Part 27.
Syntheses and optical properties of some iron, ruthenium and osmium
alkynyl complexes. Inorg. Chim. Acta (2003), 352, 9-18.
http://dx.doi.org/10.1016/S0020-1693(03)00126-9
Powell CE, Cifuentes MP, Morrall JPL, Stranger R, Humphrey
MG, Samoc M, Luther-Davies B, Heath GA Organometallic complexes for
nonlinear optics. 30. Electrochromic linear and nonlinear optical
properties of alkynylbis(diphosphine)ruthenium complexes. J. Am.
Chem. Soc. (2003), 125(2), 602-610. http://dx.doi.org/10.1021/ja0277125
Powell CE, Humphrey MG, Cifuentes MP, Morrall JP, Samoc M,
Luther-Davies B Organometallic complexes for nonlinear optics. 33.
Electrochemical switching of the third-order nonlinearity observed by
simultaneous femtosecond degenerate four-wave mixing and pump-probe
measurements.J. Phys. Chem. A (2003), 107(51), 11264-11266.
http://dx.doi.org/10.1021/jp0366217
Usher AJ, Humphrey MG, Willis AC Mixed-metal cluster
chemistry. 24. Isocyanide derivatives of
[MoIr3(μ-CO)3(CO)8(η-C5H5)]
and
[Mo2Ir2(μ-CO)3(CO)7(η-C5H5)2];
X-ray crystal structures of
[MoIr3(μ-CO)3(CO)7(L)(η-C5H5)]
(L = CNBut,
CNC6H3Me2-2,6) and
[Mo2Ir2(μ-CO)2(CNBut)2(CO)6(η-C5H5)2].
J. Organomet. Chem. (2003), 678(1-2), 72-81. http://dx.doi.org/10.1016/S0022-328X(03)00438-8
Usher AJ, Humphrey MG, Willis AC Mixed-metal cluster chemistry. 25. Mixed ligand derivatives of MoIr3(μ-CO)3(CO)8(η-C5R5) (R = H, Me) and Mo2Ir2(μ-CO)3(CO)7(η-C5H5)2; X-ray crystal structures of MoIr3(μ-CO)3(CO)6(PPh3)2(η-C5Me5) and Mo2Ir2(μ4-η2-PhC2Ph)(μ-CO)4(CNBut)(CO)3(η-C5H5)2. J. Organomet. Chem. (2003), 682(1-2), 41-48. http://dx.doi.org/10.1016/S0022-328X(03)00692-2
Freydank AC, Humphrey MG, Friedrich RW, Luther-Davies B
Synthesis and optical characterization of unsymmetrical
oligophenylenevinylenes.Tetrahedron (2002), 58(7), 1425-1432.
http://dx.doi.org/10.1016/S0040-4020(02)00003-0
Garcia MH, Robalo MP, Dias AR, Duarte MT, Wenseleers W,
Aerts G, Goovaerts E, Cifuentes MP, Hurst S, Humphrey MG, Samoc M,
Luther-Davies B Synthesis and nonlinear optical properties of
η5-monocyclopentadienyliron(II) acetylide derivatives.
X-ray crystal structures of
[Fe(η5-C5H5)(DPPE)(p-C≡CC6H4NO2)]
and
[Fe(h5-C5H5)(DPPE){(E)-p-C≡CC6H4C(H)=C(H)C6H4NO2}].
Organometallics (2002), 21(10), 2107-2118. http://dx.doi.org/10.1021/om0104619
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Green M, ed. Specialist
Periodical Reports Vol. 30, Royal Society of Chemistry: Cambridge, UK
(2002), 219-281. http://dx.doi.org/10.1039/9781847554192-00219
Humphrey MG, McDonagh AM, Houbrechts S, Asselberghs I,
Persoons A, Wada T, Sasabe H, Samoc M, Luther-Davies B From NLO-active
alkynylmetal complexes to organometallic dendrimers. In
Hyper-Structured Molecules III - Chemistry, Physics and
Applications, Sasabe H, ed. Gordon and Breach: Reading, UK (2002),
90-99.
Hurst SK, Cifuentes MP, Humphrey MG A rapid convergent
approach to organometallic dendrimers: sterically-controlled dendron
synthesis.Organometallics (2002), 21(12), 2353-2355.
http://dx.doi.org/10.1021/om0202120
Hurst SK, Cifuentes MP, McDonagh AM, Humphrey MG, Samoc M,
Luther-Davies B, Asselberghs I, Persoons A Organometallic complexes for
nonlinear optics. Part 25. Quadratic and cubic hyperpolarizabilities of
some dipolar and quadrupolar gold and ruthenium complexes. J.
Organomet. Chem. (2002), 642(1-2), 259-267. http://dx.doi.org/10.1016/S0022-328X(01)01281-5
Hurst SK, Humphrey MG, Isoshima T, Wostyn K, Asselberghs I,
Clays K, Persoons A, Samoc M, Luther-Davies B Organometallic complexes
for nonlinear optics. 28. Dimensional evolution of quadratic and cubic
optical nonlinearities in stilbenylethynylruthenium
complexes.Organometallics (2002), 21(10), 2024-2026.
http://dx.doi.org/10.1021/om020008c
Lucas NT, Blitz JP, Petrie S, Stranger R, Humphrey MG, Heath
GA, Otieno-Alego V Mixed-metal cluster chemistry. 19. Crystallographic,
spectroscopic, electrochemical, spectroelectrochemical and theoretical
studies of systematically varied tetrahedral group 6-iridium clusters.
J. Am. Chem. Soc. (2002), 124(18), 5139-5153. http://dx.doi.org/10.1021/ja0173829
Lucas NT, Humphrey MG
Decacarbonylbis(methylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum
and
decacarbonylbis(tetramethylcyclopentadienyl)-tetrahedro-diiridiumdimolybdenum
dichloromethane hemisolvate. Acta Crystallogr. C (2002), 58(3),
m171-m173. http://dx.doi.org/10.1107/S0108270102000057
Lucas NT, Whittall IR, Humphrey MG
Undecacarbonyl(methylcyclopentadienyl)-tetrahedro-triiridiummolybdenum,
undecacarbonyl(tetramethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum
and
undecacarbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum.
Acta Crystallogr. C (2002) 58(4), m249-m251. http://dx.doi.org/10.1107/S0108270101020558
Samoc M, Samoc A, Luther-Davies B, Humphrey MG, Wong M-S
Third-order optical nonlinearities of oligomers, dendrimers and
polymers derived from solution Z-scan studies. Opt. Mater.
(2002), 21(1-3), 485-488. http://dx.doi.org/10.1016/S0925-3467(02)00187-8
Feliz M, Garriga JM, Llusar R, Uriel S, Humphrey MG, Lucas
NT, Samoc M, Luther-Davies B Synthesis, structure and optical limiting
properties of heterobimetallic [M3CuS4] cuboidal
clusters (M = Mo or W) with terminal phosphine ligands.Inorg.
Chem. (2001), 40(24), 6132-6138. http://dx.doi.org/10.1021/ic010098y
Humphrey MG, Cifuentes MP Organo-transition metal cluster
complexes. In Organometallic Chemistry. Green M, ed. Specialist
Periodical Reports Vol. 29, Royal Society of Chemistry: Cambridge, UK
(2001), 289-349. http://dx.doi.org/10.1039/9781847554185-00289
Hurst SK, Cifuentes MP, Morrall JPL, Lucas NT, Whittall IR,
Humphrey MG, Asselberghs I, Persoons A, Samoc M, Luther-Davies B, Willis
AC Organometallic complexes for nonlinear optics. 22. Quadratic and
cubic hyperpolarizabilities of trans-bis(bidentate
phosphine)ruthenium σ-arylvinylidene and σ-arylalkynyl
complexes.Organometallics (2001), 20(22), 4664-4675.
http://dx.doi.org/10.1021/om0101700
Hurst SK, Lucas NT, Cifuentes MP, Humphrey MG, Samoc M,
Luther-Davies B, Asselberghs I, Van Boxel R, Persoons A Organometallic
complexes for nonlinear optics. Part 23. Quadratic and cubic
hyperpolarizabilities of acetylide and vinylidene complexes derived from
protected and free formylphenylacetylenes. J. Organomet. Chem.
(2001), 633(1-2), 114-124. http://dx.doi.org/10.1016/S0022-328X(01)01077-4
Hurst SK, Lucas NT, Humphrey MG, Asselberghs I, Persoons A
Organometallic complexes for nonlinear optics. XXVI. Quadratic
hyperpolarizabilities of some 4-methoxytetrafluorophenylalkynyl gold and
ruthenium complexes. Aust. J. Chem. (2001), 54(7), 447-452.
http://dx.doi.org/10.1071/CH01108
Lucas NT, Cifuentes MP, Nguyen LT, Humphrey MG Ruthenium
cluster chemistry with
Ph2PC6H4-4-C≡CH. J. Cluster
Sci. (2001), 12(1), 201-221. http://dx.doi.org/10.1023/A:1016683331367
Lucas NT, Humphrey MG, Rae AD Mixed-metal cluster
chemistry. 16. Syntheses of oligourethanes containing clusters in the
backbone.Macromolecules (2001), 34(18), 6188-6195. http://dx.doi.org/10.1021/ma0104480
Lucas NT, Notaras EGA, Humphrey MG
W2Ir2(CO)10(η5-C5H4Me)2.
Acta Crystallogr. E (2001), 57(4), m132-m133. http://dx.doi.org/10.1107/S1600536801003750
Lucas NT, Notaras EGA, Humphrey MG
W2Ir2(μ4-η2-C2Ph2)(μ-CO)4(CO)4(η-C5H4Me)2.
Acta Crystallogr. E (2001), 57(4), m143-m144. http://dx.doi.org/10.1107/S1600536801004123
Mata JA, Moliner V, Peris EV, Cifuentes MP, Humphrey MG,
Samoc M, Luther-Davies B Syntheses, structures and nonlinear optical
properties of ferrocenyl complexes with arylethenyl
substituents.Eur. J. Inorg. Chem. (2001), (8), 2113-2122.
http://dx.doi.org/10.1002/1099-0682(200108)2001:8<2113::AID-EJIC2113>3.0.CO;2-I
McDonagh AM, Deeble GJ, Hurst S, Cifuentes MP, Humphrey MG
Ruthenium vinylidene and acetylide complexes - an advanced
undergraduate multi-technique inorganic/organometallic chemistry
experiment.J. Chem. Educ. (2001), 78(2), 232-234. http://jchemed.chem.wisc.edu/Journal/Issues/2001/Feb/abs232.html
Notaras EGA, Lucas NT, Blitz JP, Humphrey MG Mixed-metal
cluster chemistry. Part 17. Syntheses of
WIr3(CO)11(η-C5H4Me)
and its reactivity towards diphenylacetylene. J. Organomet.
Chem. (2001), 631(1-2), 143-150. http://dx.doi.org/10.1016/S0022-328X(01)01049-X
Notaras EGA, Lucas NT, Humphrey MG Mixed-metal cluster
chemistry. Part 18. Synthesis and crystal structure of
W3Ir3(μ4-η2-CO)(μ-CO)(CO)10(μ-C5H4Me)3.
J. Organomet. Chem. (2001), 631(1-2), 139-142. http://dx.doi.org/10.1016/S0022-328X(01)01048-8
Samoc M, Humphrey MG, Cifuentes MP, McDonagh AM, Powell CE,
Heath GA, Luther-Davies, B Third-order optical nonlinearities of
organometallics: influence of dendritic geometry on the nonlinear
properties and electrochromic switching of nonlinear
absorption.SPIE Proc., Int. Soc. Opt. Eng. (2001), 4461, 65-77.
http://dx.doi.org/10.1117/12.449817
Cifuentes MP, Driver J, Humphrey MG, Asselberghs I, Persoons
A, Samoc M, Luther-Davies B Organometallic complexes for nonlinear
optics. Part 18. Molecular quadratic and cubic hyperpolarizabilities of
aryldiazovinylidene complexes. J. Organomet. Chem. (2000),
607(1-2), 72-77. http://dx.doi.org/10.1016/S0022-328X(00)00212-6
Delfs CD, Stranger R, Humphrey MG, McDonagh AM Trends in
back-bonding in the series
trans-[M(C≡CR)Cl(PH3)4] (M = Fe, Ru,
Os; R = H, Ph, C6H4NO2-4). J.
Organomet. Chem. (2000), 607(1-2), 208-212. http://dx.doi.org/10.1016/S0022-328X(00)00349-1
Humphrey MG Gold complexes for nonlinear optics.
Gold Bull. (2000), 33(3), 98-102. http://www.goldbulletin.org/archive/issue/11/issue_3_volume_33
Lucas NT, Powell CE, Humphrey MG
cis,cis,cis-(Acetato-O,O')bis{1,2-bis(diphenylphosphino)ethane-P,P'}ruthenium(II)
hexafluorophosphate dimethanol solvate. Acta Crystallogr. C
(2000), 56(9), e392-e393. http://dx.doi.org/10.1107/S0108270100011082
McDonagh AM, Cifuentes MP, Humphrey MG, Houbrechts S, Maes
J, Persoons A, Samoc M, Luther-Davies B Organometallic complexes for
nonlinear optics. Part 21. Syntheses and quadratic hyperpolarizabilities
of alkynyl complexes containing optically active
1,2-bis(methylphenylphosphino)benzene ligands. J. Organomet.
Chem. (2000), 610(1-2), 71-79. http://dx.doi.org/10.1016/S0022-328X(00)00420-4
McDonagh AM, Cifuentes MP, Lucas NT, Humphrey MG, Houbrechts
S, Persoons A Organometallic complexes for nonlinear optics. Part 19.
Syntheses and molecular quadratic hyperpolarizabilities of
indoanilinoalkynyl-ruthenium complexes. J. Organomet. Chem.
(2000), 605(2), 184-192. http://dx.doi.org/10.1016/S0022-328X(00)00312-0
McDonagh AM, Lucas NT, Cifuentes MP, Humphrey MG, Houbrechts
S, Persoons A Organometallic complexes for nonlinear optics. Part 20.
Syntheses and molecular quadratic hyperpolarizabilities of alkynyl
complexes derived from
(E)-4,4'-HC≡CC6H4N=NC6H4NO2.J.
Organomet. Chem. (2000), 605(2), 193-201. http://dx.doi.org/10.1016/S0022-328X(00)00311-9
Vicente J, Chicote MT, Abrisqueta MD, Ramírez de
Arellano MC, Jones PG, Humphrey MG, Cifuentes MP, Samoc M, Luther-Davies B
Syntheses, structure, and molecular cubic hyperpolarizabilities of
systematically varied ethynylgold(I) complexes.Organometallics
(2000), 19(16), 2968-2974. http://dx.doi.org/10.1021/om000093t
Waterman SM, Lucas NT, Humphrey MG "Very mixed"-metal
carbonyl clusters. In Advances in Organometallic Chemistry Vol.
46. West R, Hill AF, eds. Academic Press: San Diego, USA (2000), pp
47-143. http://dx.doi.org/10.1016/S0065-3055(00)46002-8
Houbrechts S, Wada T, Sasabe H, Morrall JPL, Whittall IR,
McDonagh AM, Humphrey MG, Persoons A Novel organometals for nonlinear
optics: octopolar alkynylmetal complexes. Nonlinear Optics
(1999), 22, 165-168.
McDonagh AM, Humphrey MG, Samoc M, Luther-Davies B
Organometallic complexes for nonlinear optics. 17. Synthesis,
third-order optical nonlinearities, and two-photon absorption cross
section of an alkynylruthenium dendrimer. Organometallics
(1999), 18(25), 5195-5197. http://dx.doi.org/10.1021/om9908130
McDonagh AM, Humphrey MG, Samoc M, Luther-Davies B,
Houbrechts S, Wada T, Sasabe H, Persoons A Organometallic complexes for
nonlinear optics. 16. Second and third order optical nonlinearities of
octopolar alkynylruthenium complexes. J. Am. Chem. Soc. (1999),
121(6), 1405-1406. http://dx.doi.org/10.1021/ja982965c
Vicente J, Chicote MT, González-Herrero P, Jones PG,
Humphrey MG, Cifuentes MP, Samoc M, Luther-Davies B Complexes with
S-donor ligands. 7. New 1,1-ethylenedithiolato complexes of thallium(I),
gold(I) and gold(III). Syntheses, structure and cubic
hyperpolarizabilities. Inorg. Chem. (1999), 38(22), 5018-5026.
http://dx.doi.org/10.1021/ic990379u
Waterman SM, Humphrey MG Mixed-metal cluster chemistry.
10. Isomer distribution and ligand fluxionality at
CpWIr3(μ-CO)3(CO)8-n(PR3)n
(n = 1, 2; R = Ph, Me). Organometallics (1999), 18(16),
3116-3127. http://dx.doi.org/10.1021/om9902885
Waterman SM, Humphrey MG, Hockless DCR Mixed-metal
cluster chemistry XII: isocyanide derivatives of
[CpWIr3(CO)11]; X-ray crystal structure of
[CpWIr3(CO)9(CNC6H3Me2-2,6)2].
J. Organomet. Chem. (1999), 579(1-2), 75-82. http://dx.doi.org/10.1016/S0022-328X(98)01200-5
Waterman SM, Humphrey MG, Hockless DCR Mixed-metal
cluster chemistry. Part 14: reaction of
[Cp2W2Ir2(CO)10] with
trimethylphosphite; X-ray crystal structures of
[Cp2W2Ir2(μ-CO)3(CO)5{P(OMe)3}2]
and two modifications of
[CpWIr3(μ-CO)3(CO)7{P(OMe)3}].
J. Organomet. Chem. (1999), 582(2), 310-318. http://dx.doi.org/10.1016/S0022-328X(99)00075-3
Waterman SM, Humphrey MG, Lee J Mixed-metal cluster
chemistry 15: some bidentate phosphine chemistry of tungsten-iridium
clusters. J. Organomet. Chem. (1999), 589(2), 226-233.
http://dx.doi.org/10.1016/S0022-328X(99)00406-4
Waterman SM, Humphrey MG, Lee J, Ball GE, Hockless DCR
Mixed-metal cluster chemistry. 13. Syntheses and isomer distribution
studies of
Cp2W2Ir2(μ-CO)3(CO)7-n(PR3)n
(n = 1, 2; R = Ph, Me); X-ray crystal structure of
Cp2W2Ir2(μ-CO)3(CO)6(PPh3).
Organometallics (1999), 18(13), 2440-2451. http://dx.doi.org/10.1021/om9810246
Whittall IR, McDonagh AM, Humphrey MG, Samoc M
Organometallic complexes in nonlinear optics II: third-order
nonlinearities and optical limiting studies. In Advances in
Organometallic Chemistry Vol. 43. Stone FGA, West R, Hill AF, eds.
Academic Press: San Diego, USA (1999), pp 349-405. http://dx.doi.org/10.1016/S0065-3055(08)60673-5
Cifuentes MP, Waterman SM, Humphrey MG, Heath GA, Skelton
BW, White AH, Perera MPS, Williams ML High nuclearity ruthenium
carbonyl cluster chemistry. VII. Synthesis, NMR studies, electrochemistry
and X-ray crystal structure of
[PPN][Ru8(μ8-P)(CO)22]. J.
Organomet. Chem. (1998), 565(1-2), 193-200. http://dx.doi.org/10.1016/S0022-328X(98)00452-5
Houbrechts S, Boutton C, Clays K, Persoons A, Whittall IR,
Naulty RH, Cifuentes MP, Humphrey MG Novel organometallic compounds for
nonlinear optics: metal σ-phenyl and pyridyl acetylide complexes.
J. Nonlinear Opt. Phys. Mater. (1998), 7(1), 113-120. http://dx.doi.org/10.1142/S0218863598000090
Humphrey MG, ed. "Special Issue dedicated to M.I.
Bruce". J. Organomet. Chem. (1998), 565(1-2), 1-310.
Humphrey MG Preface. J. Organomet.
Chem. (1998), 565(1-2), 1-2. http://dx.doi.org/10.1016/S0022-328X(98)00437-9
McDonagh AM, Humphrey MG, Hockless DCR Preparation of
cis- and
trans-[OsCl2(Me2SO)4], and X-ray
crystal structures of the all-S-bound isomers. Aust. J. Chem.
(1998), 51(9), 807-811. http://dx.doi.org/10.1071/C98017
Naulty RH, McDonagh AM, Whittall IR, Cifuentes MP, Humphrey
MG, Houbrechts S, Maes J, Persoons A, Heath GA, Hockless DCR
Organometallic complexes for nonlinear optics. 15. Molecular quadratic
hyperpolarizabilities of
trans-bis{bis(diphenylphosphino)methane}ruthenium σ-aryl and
σ-pyridyl-acetylides: X-ray crystal structure of
trans-[Ru(2-C≡CC5H3N-5-NO2)Cl(dppm)2].
J. Organomet. Chem. (1998), 563(1-2), 137-146. http://dx.doi.org/10.1016/S0022-328X(98)00573-7
Waterman SM, Humphrey MG, Hockless DCR Mixed-metal
cluster chemistry VIII: phosphite substitution at
[CpWIr3(CO)11]; X-ray
crystal structure of
[CpWIr3(μ-CO)3(CO)6{P(OPh)3}2].J.
Organomet. Chem. (1998), 555(1), 25-33. http://dx.doi.org/10.1016/S0022-328X(97)00686-4
Waterman SM, Humphrey MG, Hockless DCR Mixed-metal
cluster chemistry. IX. Alkylarylphosphine derivatives of
[CpWIr3(CO)11] and X-ray crystal structure of
[CpWIr3(μ-CO)3(CO)7(PMe2Ph)].
J. Organomet. Chem. (1998), 565(1-2), 81-95. http://dx.doi.org/10.1016/S0022-328X(98)00445-8
Waterman SM, Humphrey MG, Tolhurst V-A, Bruce MI, Low PJ,
Hockless DCR Mixed-metal cluster chemistry. 11. Reactions of
tungsten-iridium clusters with terminal alkynes and tungsten
acetylides; X-ray crystal structures of
Cp2W2Ir2(μ4-η2-HC2Ph)(μ-CO)4(CO)4
and
Cp2W2Ir3(μ4-η2-C2C6H4Me-4)(μ-CO)(CO)9.
Organometallics (1998), 17(26), 5789-5795. http://dx.doi.org/10.1021/om980692o
Whittall IR, Humphrey MG, Hockless DCR Structural
systematics of metal acetylide complexes. II. X-ray studies of some nickel
σ-acetylide complexes. Aust. J. Chem. (1998), 51(3), 219-227.
http://dx.doi.org/10.1071/C97082
Whittall IR, McDonagh AM, Humphrey MG, Samoc M
Organometallic complexes in nonlinear optics I: second-order
nonlinearities. In Advanced Organometallic Chemistry Vol. 42,
Stone FGA, West R, eds. Academic Press: San Diego, USA (1998), pp 291-362.
http://dx.doi.org/10.1016/S0065-3055(08)60545-6
Wong MS, Samoc M, Samoc A, Luther-Davies B, Humphrey MG
Synthesis and properties of highly soluble third-order optically
nonlinear chromophores and methacrylate monomer based on
distyrylbenzene.J. Mater. Chem. (1998), 8(9), 2005-2009.
http://dx.doi.org/10.1039/a803229g
Cifuentes MP, Humphrey MG, McGrady JE, Smith PJ, Stranger R,
Murray KS, Moubaraki B High nuclearity ruthenium carbonyl cluster
chemistry. 5. Local density functional, electronic spectroscopy, magnetic
susceptibility, and electron paramagnetic resonance studies on
(carbido)decaruthenium carbonyl clusters. J. Am. Chem. Soc.
(1997), 119(11), 2647-2655. http://dx.doi.org/10.1021/ja9602197
Lucas NT, Humphrey MG, Healy PC, Williams ML Mixed-metal
cluster chemistry VII: some phosphine and alkyne chemistry of
Cp2Mo2Ir2(CO)10; X-ray crystal
structures of
Cp2Mo2Ir2(μ-CO)3(CO)6(PMe3)
and
Cp2Mo2Ir2(μ4-η2-HC2Ph)(μ-CO)4(CO)4.J.
Organomet. Chem. (1997), 545-546, 519-530. http://dx.doi.org/10.1016/S0022-328X(97)00346-X
Lucas NT, Humphrey MG, Hockless DCR Mixed-metal cluster
chemistry V. Syntheses and X-ray crystal structure of
Cp2Mo2Ir2(μ3-CO)(μ-CO)5(CO)4.J.
Organomet. Chem. (1997), 535(1-2), 175-181. http://dx.doi.org/10.1016/S0022-328X(97)00032-6
Lucas NT, Whittall IR, Humphrey MG, Hockless DCR, Perera
MPS, Williams ML Mixed-metal cluster chemistry VI. Phosphine
substitution at CpMoIr3(μ-CO)3(CO)8;
X-ray crystal structure of
CpMoIr3(μ-CO)3(CO)7(PPh3).
J. Organomet. Chem. (1997), 540(1-2), 147-154. http://dx.doi.org/10.1016/S0022-328X(97)00111-3
McDonagh AM, Humphrey MG, Hockless DCR Selective
preparation of cis- or
trans-dichlorobis{(R,R)-1,2-phenylenebis(methylphenylphosphine-P)}osmium(II)
from dimethylsulfoxide complex precursors. Tetrahedron:
Asymmetry (1997), 8(21), 3579-3583. http://dx.doi.org/10.1016/S0957-4166(97)00468-0
McGrady JE, Lovell T, Stranger R, Humphrey MG Bonding of
η1-acetylide ligands to electron-rich ruthenium centers: can
electron-withdrawing ligands induce significant metal-to-ligand
back-bonding? Organometallics (1997), 16(18), 4004-4011.
http://dx.doi.org/10.1021/om970212d
Naulty RH, Cifuentes MP, Humphrey MG, Houbrechts S, Boutton
C, Persoons A, Heath GA, Hockless DCR, Luther-Davies B, Samoc M
Syntheses and quadratic hyperpolarizabilities of some
(pyridylalkynyl)metal complexes: crystal structures of
[Ni{2-(C≡C)C5H3NNO2-5}(PPh3)(η-C5H5)],
[Au{2-(C≡C)C5H3NNO2-5}(PPh3)]
and [Au{2-(C≡C)C5H4N}(PPh3)]
(Organometallic complexes for nonlinear optics. 13). J. Chem. Soc.,
Dalton Trans. (1997), (22), 4167-4174. http://dx.doi.org/10.1039/a702249b
Whittall IR, Cifuentes MP, Humphrey MG, Luther-Davies B,
Samoc M, Houbrechts S, Persoons A, Heath GA, Hockless DCR
Organometallic complexes for nonlinear optics. X. Molecular quadratic
and cubic hyperpolarizabilities of systematically varied
(cyclopentadienyl)bis(phosphine)ruthenium σ-arylacetylides: X-ray crystal
structure of
Ru(4,4'-C≡CC6H4CH=CHC6H4NO2)(PPh3)2(η-C5H5).
J. Organomet. Chem. (1997), 549(1-2), 127-137. http://dx.doi.org/10.1016/S0022-328X(97)00411-7
Whittall IR, Cifuentes MP, Humphrey MG, Luther-Davies B,
Samoc M, Houbrechts S, Persoons A, Heath GA, Bogsányi D
Organometallic complexes for nonlinear optics. 11. Molecular quadratic
and cubic hyperpolarizabilities of systematically varied
(cyclopentadienyl)(triphenylphosphine)nickel
σ-arylacetylides.Organometallics (1997), 16(12), 2631-2637.
http://dx.doi.org/10.1021/om961066z
Whittall IR, Humphrey MG, Hockless DCR Structural
systematics of metal acetylide complexes: X ray studies of some
'extended-chain' gold σ-acetylide complexes. Aust. J. Chem.
(1997), 50(10), 991-998. http://dx.doi.org/10.1071/C97049
Whittall IR, Humphrey MG, Houbrechts S, Maes J, Persoons A,
Schmid S, Hockless DCR Organometallic complexes for nonlinear optics.
14. Syntheses and second-order nonlinear optical properties of ruthenium,
nickel and gold σ-acetylides of 1,3,5-triethynylbenzene: X-ray crystal
structures of
1-(HC≡C)-3,5-C6H3(trans-C≡CRuCl(dppm)2)2
and
1,3,5-C6H3(C≡CAu(PPh3))3.
J. Organomet. Chem. (1997), 544(2), 277-283. http://dx.doi.org/10.1016/S0022-328X(97)00320-3
Whittall IR, Humphrey MG, Samoc M, Luther-Davies B
Organometallic complexes for nonlinear optics. Part 9. Molecular cubic
hyperpolarizabilities of systematically varied (triphenylphosphine)gold
σ-arylacetylide complexes. Angew. Chem. (1997), 109(4),
386-388. http://dx.doi.org/10.1002/ange.19971090417
Whittall IR, Humphrey MG, Samoc M, Luther-Davies B, Hockless
DCR Organometallic complexes for nonlinear optics XII. Syntheses and
second-order susceptibilities of (neomenthyldiphenylphosphine)gold
σ-arylacetylides: X-ray crystal structures of Au(C≡CPh)(nmdpp) and
Au{(E)-4,4'-C≡CC6H4CH=CHC6H4NO2}(nmdpp).
J. Organomet. Chem. (1997), 544(2), 189-196. http://dx.doi.org/10.1016/S0022-328X(97)00196-4
Cifuentes MP, Humphrey MG, Skelton BW, White AH High
nuclearity ruthenium carbonyl cluster chemistry III. Synthesis of
[Ru10(μ-H)(μ6-C)(CO)24]-, its
reactivity towards triphenylphosphine, and ligand dynamics on the
resulting decaruthenium anionic clusters. J. Organomet. Chem.
(1996), 507(1-2), 163-178. http://dx.doi.org/10.1016/0022-328X(95)05693-J
Cifuentes MP, Humphrey MG, Skelton BW, White AH Ruthenium
clusters with nitrogen ligands V. Pyridyl ligands on triruthenium cores.
X-ray structures of
Ru3(μ-H)2(μ-NC5H4)2(CO)8
and
Ru3(μ3-η2-PPhCH2PPh2)(μ-NC5H4)(CO)8.
J. Organomet. Chem. (1996), 513(1-2), 201-211. http://dx.doi.org/10.1016/0022-328X(95)05912-9
Cifuentes MP, Humphrey MG, Willis AC High nuclearity
ruthenium carbonyl cluster chemistry IV: reactivity of
[Ru10(μ-H)(μ6-C)(CO)24]-
towards trimethylphosphite or bis(diphenylphosphino)acetylene. X-ray
structure of
[PPh4][Ru10(μ-H)(μ6-C)(CO)22{P(OMe)3}2].
J. Organomet. Chem. (1996), 513(1-2), 85-95. http://dx.doi.org/10.1016/0022-328X(95)05896-W
Hockless DCR, Whittall IR, Humphrey MG
Chloro(η5-cyclopentadienyl)(triphenylphosphine)nickel(II).Acta
Crystallogr. C (1996), 52(3), 535-537. http://dx.doi.org/10.1107/S0108270195011103
Hockless DCR, Whittall IR, Humphrey MG (E)- and
(Z)-4-ethynyl-4'-nitrostilbene.Acta Crystallogr.
C (1996), 52(12), 3222-3224. http://dx.doi.org/10.1107/S0108270196009845
Hockless DCR, Wild SB, McDonagh AM, Whittall IR, Humphrey MG
trans-Dichlorobis[(R,R)-1,2-phenylenebis(methylphenylphosphine-P)]ruthenium(II).
Acta Crystallogr. C (1996), 52(7), 1639-1641. http://dx.doi.org/10.1107/S0108270196003009
Houbrechts S, Clays KJ, Persoons A, Cadierno V, Gamasa MP,
Gimeno J, Whittall IR, Humphrey MG New organometallic materials for
nonlinear optics: metal σ-arylacetylides. SPIE Proc., Int. Soc.
Opt. Eng. (1996), 2852, 98-108. http://dx.doi.org/10.1117/12.256164
Humphrey MG Metal acetylides for nonlinear optics?
Chem. Aust. (1996), 63, 442-445.
McDonagh AM, Cifuentes MP, Whittall IR, Humphrey MG, Samoc
M, Luther-Davies B, Hockless DCR Organometallic complexes for nonlinear
optics VII. Cubic optical nonlinearities of octahedral
trans-bis{bis(diphenylphosphino)methane}ruthenium acetylide
complexes; X-ray crystal structure of
trans-[Ru(C≡CPh)(4-C≡CC6H4NO2)(dppm)2].
J. Organomet. Chem. (1996), 526(1), 99-103. http://dx.doi.org/10.1016/S0022-328X(96)06469-8
McDonagh AM, Whittall IR, Humphrey MG, Hockless DCR, Skelton
BW, White AH, Organometallic complexes for nonlinear optics VI.
Syntheses of rigid-rod ruthenium σ-acetylide complexes bearing strong
acceptor ligands; X-ray crystal structures of
trans-[Ru(C≡CC6H4NO2-4)2(dppm)2]
and
trans-[Ru(C≡CC6H4C6H4NO2-4,4')2(dppm)2].
J. Organomet. Chem. (1996), 523(1), 33-40. http://dx.doi.org/10.1016/0022-328X(96)06384-X
McDonagh AM, Whittall IR, Humphrey MG, Skelton BW, White AH
Organometallic complexes for nonlinear optics V. Syntheses and
computationally-derived quadratic nonlinearities of
trans-[Ru(C≡CC6H4R-4)Cl(dppm)2]
(R = H, NO2, C6H4NO2-4,
CH=CHC6H4NO2-4,(E)); X-ray crystal
structure of
trans-[Ru(C≡CC6H4C6H4NO2-4,4')Cl(dppm)2].
J. Organomet. Chem. (1996), 519(1-2), 229-235. http://dx.doi.org/10.1016/S0022-328X(96)06197-9
Waterman SM, Humphrey MG, Hockless DCR Mixed-metal
cluster chemistry. 4. Synthesis and X-ray structure of
Cp3W3Ir4(μ-H)(CO)12.
Organometallics (1969), 15(6), 1745-1748. http://dx.doi.org/10.1021/om950802g
Waterman SM, Humphrey MG, Tolhurst V-A, Skelton BW, White
AH, Hockless DCR Mixed-metal cluster chemistry. 2. Site-selective
substitution of CpWIr3(CO)11 by phosphines; X-ray
crystal structures of
CpWIr3(μ-CO)3(CO)7(PPh3),
CpWIr3(μ-CO)3(CO)6(PPh3)2
and
CpWIr3(μ-CO)3(CO)7(PMe3).
Organometallics (1996), 15(3), 934-940. http://dx.doi.org/10.1021/om950554o
Waterman SM, Tolhurst V-A, Humphrey MG, Skelton BW, White AH
Mixed-metal cluster chemistry III. P-C activation at
tungsten-triiridium cores; X-ray crystal structures of
CpWIr3{μ3-η2-PPh(C6H4)}(m-CO)2(CO)7
and
CpWIr3{μ3-η2-PPh(C6H4)}(μ-CO)2(CO)6(PPh3).
J. Organomet. Chem. (1996), 515(1-2), 89-98. http://dx.doi.org/10.1016/0022-328X(95)06070-D
Whittall IR, Humphrey MG, Persoons A, Houbrechts S
Organometallic complexes for nonlinear optics. 3. Molecular quadratic
hyperpolarizabilities of ene , imine , and azo-linked ruthenium
σ-acetylides; X-ray crystal structure of
Ru{(E)-4,4'-C≡CC6H4CH=CHC6H4NO2}(PPh3)2(η-C5H5).
Organometallics (1996), 15(7), 1935-1941. http://dx.doi.org/10.1021/om950487y
Whittall IR, Humphrey MG, Houbrechts S, Persoons A, Hockless
DCR Organometallic complexes for nonlinear optics. 8. Molecular
quadratic hyperpolarizabilities of systematically varied
(triphenylphosphine)gold σ-arylacetylide complexes: X-ray crystal
structures of Au(C≡CR)(PPh3) (R =
4-C6H4NO2,
4,4'-C6H4C6H4NO2).
Organometallics (1996), 15(26), 5738-5745. http://dx.doi.org/10.1021/om960673j